Synthesis of mono- and polynuclear perhalophenyl palladium and platinum acetylide complexes. Molecular structure of (NBu4)2[Pt2Ag2(C6F5)4(CºCPh)4].4CH2Cl2

  1. Espinet, P. 2
  2. Forniés, J. 2
  3. Martínez, F. 2
  4. Sotes, Milagros. 2
  5. Lalinde, E. 1
  6. Moreno, M.T. 1
  7. Castillo Ruiz, Alejandro del . 1
  8. Welch, A.J. 3
  1. 1 Universidad de Zaragoza
    info

    Universidad de Zaragoza

    Zaragoza, España

    ROR https://ror.org/012a91z28

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

  3. 3 University of Edinburgh
    info

    University of Edinburgh

    Edimburgo, Reino Unido

    ROR https://ror.org/01nrxwf90

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Revista:
Journal of Organometallic Chemistry

ISSN: 0022-328X

Ano de publicación: 1991

Volume: 403

Número: 1-2

Páxinas: 253-267

Tipo: Artigo

DOI: 10.1021/OM800845C SCOPUS: 2-s2.0-0000291564 GOOGLE SCHOLAR

Outras publicacións en: Journal of Organometallic Chemistry

Resumo

The reaction between [Ag(CCR)]n (R = tBu, Ph) and the appropriate mononuclear palladium or platinum substrate affords mononuclear derivatives of the type [M(C6F5)(CCR)L2] (M = Pd, Pt; R = tBu, Ph; L = PPh3, dppe). Polynuclear (NBu4)2[Pt2Ag2(C6F5)4(CCPh)4] (X = F, Cl; R = Ph, tBu) complexes are obtained by reaction between (NBu4)2[Pt2(μ-X′)2(C6X5)4] (X′ = Cl, X = F; X′ = I, X = Cl) and [Ag(CCR)]n (Pt:Ag ratio 1:2). Similar heterometallic derivatives Q2[Pt2M2(C6F5)4 (CCR)4] (Q = PMePh3, NBu4; M = Ag, Cu; R = Ph, tBu) can be prepared by reaction of Q2[cis-Pt(C6F5)2(CCR)2] with AgCl or CuCl (Pt:M ratio 1:1). The structure of (NBu4)2[Pt2Ag2(C6F5)4 (CCPh)4]·4CH2Cl2 has been determined by X-ray diffraction. © 1991.