PABLO
ESPINET RUBIO
Investigador en el periodo 1986-2021
Publicaciones en las que colabora con PABLO ESPINET RUBIO (134)
2023
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Intimate relationship between C-I reductive elimination, aryl scrambling and isomerization processes in Au(iii) complexes
Chemical Communications, Vol. 59, Núm. 14, pp. 1975-1978
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Problematic ArF-Alkynyl Coupling with Fluorinated Aryls. from Partial Success with Alkynyl Stannanes to Efficient Solutions via Mechanistic Understanding of the Hidden Complexity
Journal of the American Chemical Society, Vol. 145, Núm. 1, pp. 527-536
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Solid state luminescence of phosphine-EWO ligands with fluorinated chalcone skeletons and their PdX2 complexes: metal-promoted phosphorescence enhancement
Dalton Transactions, Vol. 52, Núm. 11, pp. 3265-3269
2022
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Pd/Cu bimetallic catalysis to access highly fluorinated biaryls from aryl halides and fluorinated arenes
Chemical communications (Cambridge, England), Vol. 58, Núm. 19, pp. 3146-3149
2021
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Expanding the Concepts Trans Influence and Back-Donation: Hybrid and Side Donations in [Cp*MIII(L)XY] (M = Rh, Ir) Complexes with CO, CN-, and CNR Ligands. A Window to Cis Influence
Inorganic Chemistry, Vol. 60, Núm. 18, pp. 14410-14417
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Striking ligand-disproportionative Cl/aryl scrambling in a simple Au(iii) system. Solvent role, driving forces and mechanisms
Chemical Communications, Vol. 57, Núm. 1, pp. 125-128
2020
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Experimental and DFT Study of the [AuAr(AsPh3)]-Catalyzed cis/trans Isomerization of [PdAr2(AsPh3)2] (Ar = C6F5or C6Cl2F3): Alternative Mechanisms and Its Switch upon Pt for Pd Substitution
Organometallics, Vol. 39, Núm. 12, pp. 2295-2303
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Experimental study of speciation and mechanistic implications when using chelating ligands in aryl-alkynyl Stille coupling
Dalton Transactions, Vol. 49, Núm. 32, pp. 11336-11345
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Kinetic study of the dynamic behavior of [M(C6F5)X(OpPyNPH3-N)] (M ) Pd, Pt; X ) C6F5, halide; n ) 1-3): Activation parameters for the restricted rotation about the m-aryl bond and for the py associative exchange
Organometallics, Vol. 16, Núm. 4, pp. 770-779
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Ranking Ligands by Their Ability to Ease (C6F5)2NiIIL → Ni0L + (C6F5)2Coupling versus Hydrolysis: Outstanding Activity of PEWO Ligands
Inorganic Chemistry, Vol. 59, Núm. 24, pp. 18287-18294
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Reactivity of Fluorinated-Chalcone Phosphines, RPEWO-F4, Induced by C-F Activation upon Coordination to PdCl2
Organometallics, Vol. 39, Núm. 6, pp. 841-847
2019
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4-Pyridylisocyanide gold(i) and gold(i)-plus-silver(i) luminescent and mechanochromic materials: The silver role
Dalton Transactions, Vol. 48, Núm. 28, pp. 10412-10416
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D8⋯d10 RhI⋯AuI interactions in Rh 2,6-xylylisocyanide complexes with [Au(CN)2]-: Bond analysis and crystal effects
Chemical Communications, Vol. 55, Núm. 34, pp. 5005-5008
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E-Z Isomerization of Phosphine-Olefin (PEWO-F4) Ligands Revealed upon PdCl2 Capture: Facts and Mechanism
Organometallics, Vol. 38, Núm. 24, pp. 4701-4707
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Intriguing Behavior of an Apparently Simple Coupling Promoter Ligand, PPh2(p-C6H4-C6F5), in Their Pd Complexes
Organometallics, Vol. 38, Núm. 19, pp. 3688-3695
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Rh I Ar/Au I Ar′ Transmetalation: A Case of Group Exchange Pivoting on the Formation of M−M′ Bonds through Oxidative Insertion
Angewandte Chemie - International Edition, Vol. 58, Núm. 11, pp. 3501-3505
2018
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Comparing Protonolysis and Transmetalation Reactions: Microcalorimetric Studies of C-AuI Bonds in [AuRL] Complexes
Inorganic Chemistry, Vol. 57, Núm. 17, pp. 11193-11200
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Coordinatively Unsaturated [RhCp∗Rf2] (Cp∗ = C5Me5; Rf = C6F3Cl2-3,5), General Precursor to Cp∗-Diaryl and Cp∗-Halo-Aryl RhIII Complexes. Observing and Testing the Effect of Cp∗ as Electronic Buffer
Organometallics, Vol. 37, Núm. 20, pp. 3533-3542
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Hidden aryl-exchange processes in stable 16e RhIII [RhCp∗Ar2] complexes, and their unexpected transmetalation mechanism
Chemical Communications, Vol. 54, Núm. 8, pp. 984-987
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Highly enantioselective addition of dimethylzinc to fluorinated alkyl ketones, and the mechanism behind it
Chemical Communications, Vol. 54, Núm. 83, pp. 11809-11812