Publications (33) FRANCISCO JAVIER NIETO ROMAN publications

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2023

  1. Enantioselective synthesis of 3-hydroxy- and 3-amino-3-alkynyl-2-oxindoles by the dimethylzinc-mediated addition of terminal alkynes to isatins and isatin-derived ketimines

    Organic and Biomolecular Chemistry, Vol. 21, Núm. 34, pp. 6940-6948

2021

  1. Dimethylzinc-mediated enantioselective addition of terminal alkynes to 1,2-diketones using perhydro-1,3-benzoxazines as ligands

    Organic and Biomolecular Chemistry, Vol. 19, Núm. 17, pp. 3859-3867

2019

  1. Synthesis of Enantiopure Oxygen- and Nitrogen-Containing Heterocycles by Diastereoselective Ring-Closing Metathesis Reaction in Perhydro-1,3-benzoxazine Derivatives

    Advanced Synthesis and Catalysis, Vol. 361, Núm. 5, pp. 1042-1063

2017

  1. Dimethylzinc-Mediated Addition of Phenylacetylene to α-Diketones Catalyzed by Chiral Perhydro-1,3-benzoxazines

    Organic Letters, Vol. 19, Núm. 7, pp. 1516-1519

2015

  1. 7-endo selenocyclization reactions on chiral 3-prenyl and 3-cinnamyl-2-hydroxymethylperhydro-1,3-benzoxazine derivatives. A way to enantiopure 1,4-oxazepanes

    Organic and Biomolecular Chemistry, Vol. 13, Núm. 34, pp. 9118-9126

2014

  1. Tandem diastereo- and enantioselective preparation of aryl and alkyl cyclopropyl carbinols with three adjacent stereocenters using perhydrobenzoxazines and diethylzinc

    Organic and Biomolecular Chemistry, Vol. 12, Núm. 2, pp. 345-354

2013

  1. Enantioselective one-pot catalytic synthesis of 4,5-epoxy-3-alkanols and 1-Phenyl-2,3-epoxy-1-alkanols from α,β-unsaturated aldehydes

    European Journal of Organic Chemistry, pp. 4863-4869

2012

  1. Enantiocontrolled synthesis of tertiary a-hydroxy-a-ynyl esters by dimethylzinc-mediated addition of alkynes to a-keto esters

    Advanced Synthesis and Catalysis, Vol. 354, Núm. 14-15, pp. 2797-2804

  2. Enantioselective addition of dimethylzinc to aldehydes catalyzed by a chiral perhydro-1,3-benzoxazine-based amino alcohol as ligand

    Synthesis, Vol. 44, Núm. 9, pp. 1343-1348

  3. Highly homogeneous stereocontrolled construction of quaternary hydroxyesters by addition of dimethylzinc to α-ketoesters promoted by chiral perhydrobenzoxazines and B(OEt) 3

    Chemistry - A European Journal, Vol. 18, Núm. 14, pp. 4375-4379

2011

  1. Asymmetric additive-free aryl addition to aldehydes using perhydrobenzoxazines as ligands and boroxins as aryl source

    Organic and Biomolecular Chemistry, Vol. 9, Núm. 19, pp. 6691-6699

2010

  1. ChemInform Abstract: A Novel Synthesis of Enantiopure Octahydropyrrolo[3,4-b]pyrroles by Intramolecular [3 + 2] Dipolar Cycloaddition on Chiral Perhydro-1,3-benzoxazines.

    ChemInform, Vol. 33, Núm. 47, pp. no-no

  2. Perhydro-1,3-benzoxazines derived from (-)-8-aminomenthol as ligands for the catalytic enantioselective addition of diethylzinc to aldehydes

    Tetrahedron Asymmetry, Vol. 21, Núm. 18, pp. 2230-2237

2009

  1. Lewis acid mediated diastereoselective keto-ene cyclization on chiral perhydro-1,3-benzoxazines: synthesis of enantiopure cis-3,4-disubstituted 3-hydroxypyrrolidines

    Tetrahedron, Vol. 65, Núm. 47, pp. 9728-9736

2006

  1. 1,4-Asymmetric induction in methoxyselenenylation of double bonds at the nitrogen side of chiral perhydro-1,3-benzoxazines promoted by nonbonded Se⋯N interactions

    Journal of Organic Chemistry, Vol. 71, Núm. 14, pp. 5388-5391

  2. An efficient and diastereoselective intramolecular 1,3-dipolar cycloaddition of cyclic azomethine ylides and nitrones

    European Journal of Organic Chemistry, pp. 3259-3265

  3. Diastereoselective synthesis of enantiopure morphelines by electrophilic selenium-induced 6-exo cyclizations on chiral 3-allyl-2-hydroxymethylperhydro-1, 3-benzoxazine derivatives

    Journal of Organic Chemistry, Vol. 71, Núm. 23, pp. 8854-8863

  4. Regio- and stereoselective methoxyselenenylation of chiral 2-vinyl perhydro-1,3-benzoxazines promoted by selenium-heteroatom nonbonded interactions

    Journal of Organic Chemistry, Vol. 71, Núm. 6, pp. 2424-2428

2005

  1. Chiral perhydro-1, 3-benzoxazines: Powerful auxiliaries in asymmetric synthesis of nitrogen heterocycles

    New methods for the asymmetric synthesis of nitrogen heterocycles (Research Signpost), pp. 65-98

  2. Diastereoselective intramolecular alder-ene reaction on chiral perhydro-1,3-benzoxazines. A rapid entry to enantiopure cis-3,4-disubstituted pyrrolidines

    Journal of Organic Chemistry, Vol. 70, Núm. 11, pp. 4332-4337