Publications (363) PABLO ESPINET RUBIO publications

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2025

  1. Opposite Effects of Added AsPh3 Reveal a Drastic Mechanistic Switch in RhI/AuI Transmetalations via Rh-Au Bonded Intermediates

    Inorganic Chemistry, Vol. 64, Núm. 27, pp. 13729-13739

2024

  1. Palladium (II) Precursors for Clean In Situ Formation of Ad Hoc Cross-Coupling Catalysts. Their Application in One-Pot/Two-Step Catalyses with 2-Biaryl-Dialkylphosphine Ligands

    Advanced Synthesis and Catalysis, Vol. 366, Núm. 19, pp. 4145-4157

2023

  1. Intimate relationship between C-I reductive elimination, aryl scrambling and isomerization processes in Au(iii) complexes

    Chemical Communications, Vol. 59, Núm. 14, pp. 1975-1978

  2. Problematic ArF-Alkynyl Coupling with Fluorinated Aryls. from Partial Success with Alkynyl Stannanes to Efficient Solutions via Mechanistic Understanding of the Hidden Complexity

    Journal of the American Chemical Society, Vol. 145, Núm. 1, pp. 527-536

  3. Solid state luminescence of phosphine-EWO ligands with fluorinated chalcone skeletons and their PdX2 complexes: metal-promoted phosphorescence enhancement

    Dalton Transactions, Vol. 52, Núm. 11, pp. 3265-3269

2022

  1. Access to luminescent mesophases of chiral gold(1>complexes by thermal or mechanic stimuli: the role of the tertiary carbon

    Journal of Materials Chemistry C, Vol. 10, Núm. 3, pp. 941-946

  2. Mesogenic [Rh(L)4](A) complexes form mesophases with RhI⋯RhI-containing and triphenylene-discotic segregated columns. Effect of RhI⋯RhI interactions and A− = [Au(CN)2]− on hole mobility

    Journal of Materials Chemistry C, Vol. 11, Núm. 4, pp. 1435-1447

  3. Pd/Cu bimetallic catalysis to access highly fluorinated biaryls from aryl halides and fluorinated arenes

    Chemical communications (Cambridge, England), Vol. 58, Núm. 19, pp. 3146-3149

  4. Triphenylene-ethylammonium tetrachlorometallate salts: multicolumnar mesophases, thermochromism and Langmuir films

    Journal of Materials Chemistry C, Vol. 10, Núm. 24, pp. 9222-9231

2021

  1. Easy wide scope access to luminescent fluorophosphoranes

    Chemical Communications, Vol. 57, Núm. 44, pp. 5458-5461

  2. Expanding the Concepts Trans Influence and Back-Donation: Hybrid and Side Donations in [Cp*MIII(L)XY] (M = Rh, Ir) Complexes with CO, CN-, and CNR Ligands. A Window to Cis Influence

    Inorganic Chemistry, Vol. 60, Núm. 18, pp. 14410-14417

  3. Selective synthesis of fluorinated biaryls by [MCl2(PhPEWO-F)] (M = Ni, Pd) catalysed Negishi cross-coupling

    Chemical Communications, Vol. 57, Núm. 83, pp. 10875-10878

  4. Striking ligand-disproportionative Cl/aryl scrambling in a simple Au(iii) system. Solvent role, driving forces and mechanisms

    Chemical Communications, Vol. 57, Núm. 1, pp. 125-128

  5. Understanding the Use of Phosphine-(EWO) Ligands in Negishi Cross-Coupling: Experimental and Density Functional Theory Mechanistic Study

    Organometallics, Vol. 40, Núm. 14, pp. 2272-2282

2020

  1. Experimental and DFT Study of the [AuAr(AsPh3)]-Catalyzed cis/trans Isomerization of [PdAr2(AsPh3)2] (Ar = C6F5or C6Cl2F3): Alternative Mechanisms and Its Switch upon Pt for Pd Substitution

    Organometallics, Vol. 39, Núm. 12, pp. 2295-2303

  2. Experimental study of speciation and mechanistic implications when using chelating ligands in aryl-alkynyl Stille coupling

    Dalton Transactions, Vol. 49, Núm. 32, pp. 11336-11345

  3. Fluorescent perylenylpyridine complexes: an experimental and theoretical study

    Dalton Transactions, Vol. 49, Núm. 38, pp. 13326-13338

  4. Fluorinated vs Nonfluorinated PR2(biaryl) Ligands and Their [AuCl(L)] Complexes: Synthesis, X-ray Structures, and Computational Study of Weak Interactions. Bond, No Bond, and beyond

    Inorganic Chemistry, Vol. 59, Núm. 22, pp. 16599-16610

  5. Ranking Ligands by Their Ability to Ease (C6F5)2NiIIL → Ni0L + (C6F5)2Coupling versus Hydrolysis: Outstanding Activity of PEWO Ligands

    Inorganic Chemistry, Vol. 59, Núm. 24, pp. 18287-18294

  6. Reactivity of Fluorinated-Chalcone Phosphines, RPEWO-F4, Induced by C-F Activation upon Coordination to PdCl2

    Organometallics, Vol. 39, Núm. 6, pp. 841-847