MARCONI NICOLAS
PEÑAS DE FRUTOS
INVESTIGADOR POSDOCTORAL MARGARITA SALAS
PABLO
ESPINET RUBIO
Researcher in the period 1986-2021
Publications by the researcher in collaboration with PABLO ESPINET RUBIO (14)
2023
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Intimate relationship between C-I reductive elimination, aryl scrambling and isomerization processes in Au(iii) complexes
Chemical Communications, Vol. 59, Núm. 14, pp. 1975-1978
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Problematic ArF-Alkynyl Coupling with Fluorinated Aryls. from Partial Success with Alkynyl Stannanes to Efficient Solutions via Mechanistic Understanding of the Hidden Complexity
Journal of the American Chemical Society, Vol. 145, Núm. 1, pp. 527-536
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Solid state luminescence of phosphine-EWO ligands with fluorinated chalcone skeletons and their PdX2 complexes: metal-promoted phosphorescence enhancement
Dalton Transactions, Vol. 52, Núm. 11, pp. 3265-3269
2021
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Expanding the Concepts Trans Influence and Back-Donation: Hybrid and Side Donations in [Cp*MIII(L)XY] (M = Rh, Ir) Complexes with CO, CN-, and CNR Ligands. A Window to Cis Influence
Inorganic Chemistry, Vol. 60, Núm. 18, pp. 14410-14417
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Striking ligand-disproportionative Cl/aryl scrambling in a simple Au(iii) system. Solvent role, driving forces and mechanisms
Chemical Communications, Vol. 57, Núm. 1, pp. 125-128
2020
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Experimental study of speciation and mechanistic implications when using chelating ligands in aryl-alkynyl Stille coupling
Dalton Transactions, Vol. 49, Núm. 32, pp. 11336-11345
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Reactivity of Fluorinated-Chalcone Phosphines, RPEWO-F4, Induced by C-F Activation upon Coordination to PdCl2
Organometallics, Vol. 39, Núm. 6, pp. 841-847
2019
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4-Pyridylisocyanide gold(i) and gold(i)-plus-silver(i) luminescent and mechanochromic materials: The silver role
Dalton Transactions, Vol. 48, Núm. 28, pp. 10412-10416
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D8⋯d10 RhI⋯AuI interactions in Rh 2,6-xylylisocyanide complexes with [Au(CN)2]-: Bond analysis and crystal effects
Chemical Communications, Vol. 55, Núm. 34, pp. 5005-5008
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E-Z Isomerization of Phosphine-Olefin (PEWO-F4) Ligands Revealed upon PdCl2 Capture: Facts and Mechanism
Organometallics, Vol. 38, Núm. 24, pp. 4701-4707
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Rh I Ar/Au I Ar′ Transmetalation: A Case of Group Exchange Pivoting on the Formation of M−M′ Bonds through Oxidative Insertion
Angewandte Chemie - International Edition, Vol. 58, Núm. 11, pp. 3501-3505
2018
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Coordinatively Unsaturated [RhCp∗Rf2] (Cp∗ = C5Me5; Rf = C6F3Cl2-3,5), General Precursor to Cp∗-Diaryl and Cp∗-Halo-Aryl RhIII Complexes. Observing and Testing the Effect of Cp∗ as Electronic Buffer
Organometallics, Vol. 37, Núm. 20, pp. 3533-3542
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Hidden aryl-exchange processes in stable 16e RhIII [RhCp∗Ar2] complexes, and their unexpected transmetalation mechanism
Chemical Communications, Vol. 54, Núm. 8, pp. 984-987
2016
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Some Singular Features of Gold Catalysis: Protection of Gold(I) Catalysts by Substoichiometric Agents and Associated Phenomena
ACS Catalysis, Vol. 6, Núm. 10, pp. 6537-6545