Argitalpenak (22) MARCONI NICOLAS PEÑAS DE FRUTOS argitalpenak

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2025

  1. Opposite Effects of Added AsPh3 Reveal a Drastic Mechanistic Switch in RhI/AuI Transmetalations via Rh-Au Bonded Intermediates

    Inorganic Chemistry

  2. Selective Stepwise Reduction of Nitrate and Nitrite to Dinitrogen or Ammonia

    Journal of the American Chemical Society, Vol. 147, Núm. 10, pp. 8444-8454

2024

  1. Challenges in the computational modelling of bimetallic C–H activation processes

    Advances in Organometallic Chemistry, Vol. 81, pp. 329-348

  2. Identity of the Silyl Ligand in an Iron Silyl Complex Influences Olefin Hydrogenation: An Experimental and Computational Study

    Inorganic Chemistry, Vol. 63, Núm. 38, pp. 17706-17713

  3. Unlocking the Metalation Applications of TMP-powered Fe and Co(II) bis(amides): Synthesis, Structure and Mechanistic Insights

    Angewandte Chemie - International Edition, Vol. 63, Núm. 24

2023

  1. Intimate relationship between C-I reductive elimination, aryl scrambling and isomerization processes in Au(iii) complexes

    Chemical Communications, Vol. 59, Núm. 14, pp. 1975-1978

  2. Problematic ArF-Alkynyl Coupling with Fluorinated Aryls. from Partial Success with Alkynyl Stannanes to Efficient Solutions via Mechanistic Understanding of the Hidden Complexity

    Journal of the American Chemical Society, Vol. 145, Núm. 1, pp. 527-536

  3. Sodium mediated deprotonative borylation of arenes using sterically demanding B(CH2SiMe3)3: unlocking polybasic behaviour and competing lateral borane sodiation

    Chemical Science, Vol. 14, Núm. 24, pp. 6538-6545

  4. Solid state luminescence of phosphine-EWO ligands with fluorinated chalcone skeletons and their PdX2 complexes: metal-promoted phosphorescence enhancement

    Dalton Transactions, Vol. 52, Núm. 11, pp. 3265-3269

2022

  1. Secondary Coordination Sphere Influences the Formation of Fe(III)-O or Fe(III)-OH in Nitrite Reduction: A Synthetic and Computational Study

    Inorganic Chemistry, Vol. 61, Núm. 21, pp. 8182-8192

  2. γ-Agostic interactions in (MesCCC)Fe-Mes(L) complexes

    Chemical Communications, Vol. 58, Núm. 69, pp. 9626-9629

2021

  1. Expanding the Concepts Trans Influence and Back-Donation: Hybrid and Side Donations in [Cp*MIII(L)XY] (M = Rh, Ir) Complexes with CO, CN-, and CNR Ligands. A Window to Cis Influence

    Inorganic Chemistry, Vol. 60, Núm. 18, pp. 14410-14417

  2. Striking ligand-disproportionative Cl/aryl scrambling in a simple Au(iii) system. Solvent role, driving forces and mechanisms

    Chemical Communications, Vol. 57, Núm. 1, pp. 125-128

2020

  1. Experimental study of speciation and mechanistic implications when using chelating ligands in aryl-alkynyl Stille coupling

    Dalton Transactions, Vol. 49, Núm. 32, pp. 11336-11345

  2. Reactivity of Fluorinated-Chalcone Phosphines, RPEWO-F4, Induced by C-F Activation upon Coordination to PdCl2

    Organometallics, Vol. 39, Núm. 6, pp. 841-847

2019

  1. 4-Pyridylisocyanide gold(i) and gold(i)-plus-silver(i) luminescent and mechanochromic materials: The silver role

    Dalton Transactions, Vol. 48, Núm. 28, pp. 10412-10416

  2. D8⋯d10 RhI⋯AuI interactions in Rh 2,6-xylylisocyanide complexes with [Au(CN)2]-: Bond analysis and crystal effects

    Chemical Communications, Vol. 55, Núm. 34, pp. 5005-5008

  3. E-Z Isomerization of Phosphine-Olefin (PEWO-F4) Ligands Revealed upon PdCl2 Capture: Facts and Mechanism

    Organometallics, Vol. 38, Núm. 24, pp. 4701-4707

  4. Rh I Ar/Au I Ar′ Transmetalation: A Case of Group Exchange Pivoting on the Formation of M−M′ Bonds through Oxidative Insertion

    Angewandte Chemie - International Edition, Vol. 58, Núm. 11, pp. 3501-3505

2018

  1. Coordinatively Unsaturated [RhCp∗Rf2] (Cp∗ = C5Me5; Rf = C6F3Cl2-3,5), General Precursor to Cp∗-Diaryl and Cp∗-Halo-Aryl RhIII Complexes. Observing and Testing the Effect of Cp∗ as Electronic Buffer

    Organometallics, Vol. 37, Núm. 20, pp. 3533-3542