Publications by the researcher in collaboration with PABLO ESPINET RUBIO (14)

2023

  1. Intimate relationship between C-I reductive elimination, aryl scrambling and isomerization processes in Au(iii) complexes

    Chemical Communications, Vol. 59, Núm. 14, pp. 1975-1978

  2. Problematic ArF-Alkynyl Coupling with Fluorinated Aryls. from Partial Success with Alkynyl Stannanes to Efficient Solutions via Mechanistic Understanding of the Hidden Complexity

    Journal of the American Chemical Society, Vol. 145, Núm. 1, pp. 527-536

  3. Solid state luminescence of phosphine-EWO ligands with fluorinated chalcone skeletons and their PdX2 complexes: metal-promoted phosphorescence enhancement

    Dalton Transactions, Vol. 52, Núm. 11, pp. 3265-3269

2021

  1. Expanding the Concepts Trans Influence and Back-Donation: Hybrid and Side Donations in [Cp*MIII(L)XY] (M = Rh, Ir) Complexes with CO, CN-, and CNR Ligands. A Window to Cis Influence

    Inorganic Chemistry, Vol. 60, Núm. 18, pp. 14410-14417

  2. Striking ligand-disproportionative Cl/aryl scrambling in a simple Au(iii) system. Solvent role, driving forces and mechanisms

    Chemical Communications, Vol. 57, Núm. 1, pp. 125-128

2020

  1. Experimental study of speciation and mechanistic implications when using chelating ligands in aryl-alkynyl Stille coupling

    Dalton Transactions, Vol. 49, Núm. 32, pp. 11336-11345

  2. Reactivity of Fluorinated-Chalcone Phosphines, RPEWO-F4, Induced by C-F Activation upon Coordination to PdCl2

    Organometallics, Vol. 39, Núm. 6, pp. 841-847

2019

  1. 4-Pyridylisocyanide gold(i) and gold(i)-plus-silver(i) luminescent and mechanochromic materials: The silver role

    Dalton Transactions, Vol. 48, Núm. 28, pp. 10412-10416

  2. D8⋯d10 RhI⋯AuI interactions in Rh 2,6-xylylisocyanide complexes with [Au(CN)2]-: Bond analysis and crystal effects

    Chemical Communications, Vol. 55, Núm. 34, pp. 5005-5008

  3. E-Z Isomerization of Phosphine-Olefin (PEWO-F4) Ligands Revealed upon PdCl2 Capture: Facts and Mechanism

    Organometallics, Vol. 38, Núm. 24, pp. 4701-4707

  4. Rh I Ar/Au I Ar′ Transmetalation: A Case of Group Exchange Pivoting on the Formation of M−M′ Bonds through Oxidative Insertion

    Angewandte Chemie - International Edition, Vol. 58, Núm. 11, pp. 3501-3505

2018

  1. Coordinatively Unsaturated [RhCp∗Rf2] (Cp∗ = C5Me5; Rf = C6F3Cl2-3,5), General Precursor to Cp∗-Diaryl and Cp∗-Halo-Aryl RhIII Complexes. Observing and Testing the Effect of Cp∗ as Electronic Buffer

    Organometallics, Vol. 37, Núm. 20, pp. 3533-3542

  2. Hidden aryl-exchange processes in stable 16e RhIII [RhCp∗Ar2] complexes, and their unexpected transmetalation mechanism

    Chemical Communications, Vol. 54, Núm. 8, pp. 984-987

2016

  1. Some Singular Features of Gold Catalysis: Protection of Gold(I) Catalysts by Substoichiometric Agents and Associated Phenomena

    ACS Catalysis, Vol. 6, Núm. 10, pp. 6537-6545