PABLO
ESPINET RUBIO
Investigador en el periodo 1986-2021
Publicaciones en las que colabora con PABLO ESPINET RUBIO (314)
2024
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Palladium (II) Precursors for Clean In Situ Formation of Ad Hoc Cross-Coupling Catalysts. Their Application in One-Pot/Two-Step Catalyses with 2-Biaryl-Dialkylphosphine Ligands
Advanced Synthesis and Catalysis, Vol. 366, Núm. 19, pp. 4145-4157
2023
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Intimate relationship between C-I reductive elimination, aryl scrambling and isomerization processes in Au(iii) complexes
Chemical Communications, Vol. 59, Núm. 14, pp. 1975-1978
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Problematic ArF-Alkynyl Coupling with Fluorinated Aryls. from Partial Success with Alkynyl Stannanes to Efficient Solutions via Mechanistic Understanding of the Hidden Complexity
Journal of the American Chemical Society, Vol. 145, Núm. 1, pp. 527-536
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Solid state luminescence of phosphine-EWO ligands with fluorinated chalcone skeletons and their PdX2 complexes: metal-promoted phosphorescence enhancement
Dalton Transactions, Vol. 52, Núm. 11, pp. 3265-3269
2022
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Access to luminescent mesophases of chiral gold(1>complexes by thermal or mechanic stimuli: the role of the tertiary carbon
Journal of Materials Chemistry C, Vol. 10, Núm. 3, pp. 941-946
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Mesogenic [Rh(L)4](A) complexes form mesophases with RhI⋯RhI-containing and triphenylene-discotic segregated columns. Effect of RhI⋯RhI interactions and A− = [Au(CN)2]− on hole mobility
Journal of Materials Chemistry C, Vol. 11, Núm. 4, pp. 1435-1447
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Pd/Cu bimetallic catalysis to access highly fluorinated biaryls from aryl halides and fluorinated arenes
Chemical communications (Cambridge, England), Vol. 58, Núm. 19, pp. 3146-3149
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Triphenylene-ethylammonium tetrachlorometallate salts: multicolumnar mesophases, thermochromism and Langmuir films
Journal of Materials Chemistry C, Vol. 10, Núm. 24, pp. 9222-9231
2021
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Easy wide scope access to luminescent fluorophosphoranes
Chemical Communications, Vol. 57, Núm. 44, pp. 5458-5461
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Expanding the Concepts Trans Influence and Back-Donation: Hybrid and Side Donations in [Cp*MIII(L)XY] (M = Rh, Ir) Complexes with CO, CN-, and CNR Ligands. A Window to Cis Influence
Inorganic Chemistry, Vol. 60, Núm. 18, pp. 14410-14417
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Selective synthesis of fluorinated biaryls by [MCl2(PhPEWO-F)] (M = Ni, Pd) catalysed Negishi cross-coupling
Chemical Communications, Vol. 57, Núm. 83, pp. 10875-10878
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Striking ligand-disproportionative Cl/aryl scrambling in a simple Au(iii) system. Solvent role, driving forces and mechanisms
Chemical Communications, Vol. 57, Núm. 1, pp. 125-128
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Understanding the Use of Phosphine-(EWO) Ligands in Negishi Cross-Coupling: Experimental and Density Functional Theory Mechanistic Study
Organometallics, Vol. 40, Núm. 14, pp. 2272-2282
2020
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Experimental and DFT Study of the [AuAr(AsPh3)]-Catalyzed cis/trans Isomerization of [PdAr2(AsPh3)2] (Ar = C6F5or C6Cl2F3): Alternative Mechanisms and Its Switch upon Pt for Pd Substitution
Organometallics, Vol. 39, Núm. 12, pp. 2295-2303
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Experimental study of speciation and mechanistic implications when using chelating ligands in aryl-alkynyl Stille coupling
Dalton Transactions, Vol. 49, Núm. 32, pp. 11336-11345
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Fluorescent perylenylpyridine complexes: an experimental and theoretical study
Dalton Transactions, Vol. 49, Núm. 38, pp. 13326-13338
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Fluorinated vs Nonfluorinated PR2(biaryl) Ligands and Their [AuCl(L)] Complexes: Synthesis, X-ray Structures, and Computational Study of Weak Interactions. Bond, No Bond, and beyond
Inorganic Chemistry, Vol. 59, Núm. 22, pp. 16599-16610
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Kinetic study of the dynamic behavior of [M(C6F5)X(OpPyNPH3-N)] (M ) Pd, Pt; X ) C6F5, halide; n ) 1-3): Activation parameters for the restricted rotation about the m-aryl bond and for the py associative exchange
Organometallics, Vol. 16, Núm. 4, pp. 770-779
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Ranking Ligands by Their Ability to Ease (C6F5)2NiIIL → Ni0L + (C6F5)2Coupling versus Hydrolysis: Outstanding Activity of PEWO Ligands
Inorganic Chemistry, Vol. 59, Núm. 24, pp. 18287-18294
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Reactivity of Fluorinated-Chalcone Phosphines, RPEWO-F4, Induced by C-F Activation upon Coordination to PdCl2
Organometallics, Vol. 39, Núm. 6, pp. 841-847