ChemInform Abstract: The Reaction of Carbanions from 3-Methyl-5-phenylisoxazole with Electrophilic Compounds.
- ALBEROLA, A. 1
- CALVO, L. 1
- RODRIGUEZ RODRIGUEZ, T. 1
- SANUDO, C. 1
-
1
Universidad de Valladolid
info
ISSN: 0931-7597
Année de publication: 2010
Volumen: 23
Número: 37
Pages: no-no
Type: Article
D'autres publications dans: ChemInform
Résumé
The reaction of the title compound (I) with the electrophiles (II) is studied in the presence of different bases.When BuLi is used mixtures of the products (III) and (IV) are formed while LICA/TMEDA only leads to (III). In the presence of LICA the product distribution (III)/(IV) depends on the halide used for the reaction. The reaction of (I) with other electrophiles, e.g. (V), also proceeds regioselectively in the presence of LICA/TMEDA.
Références bibliographiques
- ALBEROLA, (1992), J. Heterocycl. Chem., 29, pp. 445, 10.1002/jhet.5570290225