ChemInform Abstract: Multicomponent Prins Cyclization from Allylsilyl Alcohols Leading to Dioxaspirodecanes.

  1. Barbero, Asuncion 1
  2. Diez-Varga, Alberto 1
  3. Pulido, Francisco J. 1
  1. 1 Universidad de Valladolid
    info

    Universidad de Valladolid

    Valladolid, España

    ROR https://ror.org/01fvbaw18

Aldizkaria:
ChemInform

ISSN: 0931-7597

Argitalpen urtea: 2014

Alea: 45

Zenbakia: 11

Orrialdeak: no-no

Mota: Artikulua

DOI: 10.1002/CHIN.201411114 GOOGLE SCHOLAR lock_openSarbide irekia editor

Beste argitalpen batzuk: ChemInform

Garapen Iraunkorreko Helburuak

Laburpena

This reaction proceeds via an acid catalyzed Sakurai reaction followed by the formation of an oxocarbenium intermediate with a second equivalent of aldehyde. Prins cyclization and subsequent trapping of the pyranyl carbocation by the hydroxyl group generates the major reaction product

Erreferentzia bibliografikoak

  • Barbero, (2013), Org. Lett., 15, pp. 5234, 10.1021/ol402425u