JUAN ANGEL
CASARES GONZALEZ
CATEDRATICOS DE UNIVERSIDAD
PABLO
ESPINET RUBIO
Investigador no período 1986-2021
Publicacións nas que colabora con PABLO ESPINET RUBIO (46)
2022
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Pd/Cu bimetallic catalysis to access highly fluorinated biaryls from aryl halides and fluorinated arenes
Chemical communications (Cambridge, England), Vol. 58, Núm. 19, pp. 3146-3149
2020
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Experimental and DFT Study of the [AuAr(AsPh3)]-Catalyzed cis/trans Isomerization of [PdAr2(AsPh3)2] (Ar = C6F5or C6Cl2F3): Alternative Mechanisms and Its Switch upon Pt for Pd Substitution
Organometallics, Vol. 39, Núm. 12, pp. 2295-2303
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Kinetic study of the dynamic behavior of [M(C6F5)X(OpPyNPH3-N)] (M ) Pd, Pt; X ) C6F5, halide; n ) 1-3): Activation parameters for the restricted rotation about the m-aryl bond and for the py associative exchange
Organometallics, Vol. 16, Núm. 4, pp. 770-779
2019
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Intriguing Behavior of an Apparently Simple Coupling Promoter Ligand, PPh2(p-C6H4-C6F5), in Their Pd Complexes
Organometallics, Vol. 38, Núm. 19, pp. 3688-3695
2018
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Comparing Protonolysis and Transmetalation Reactions: Microcalorimetric Studies of C-AuI Bonds in [AuRL] Complexes
Inorganic Chemistry, Vol. 57, Núm. 17, pp. 11193-11200
2017
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Speciation of ZnMe2, ZnMeCl, and ZnCl2 in Tetrahydrofuran (THF), and Its Influence on Mechanism Calculations of Catalytic Processes
ACS Catalysis, Vol. 7, Núm. 5, pp. 3575-3583
2016
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ChemInform Abstract: In situ Generation of ArCu from CuF<sub>2</sub>Makes Coupling of Bulky Aryl Silanes Feasible and Highly Efficient.
ChemInform, Vol. 47, Núm. 31
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Dramatic mechanistic switch in Sn/AuI group exchanges: Transmetalation vs. oxidative addition
Chemical Communications, Vol. 52, Núm. 23, pp. 4305-4308
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In Situ Generation of ArCu from CuF2 Makes Coupling of Bulky Aryl Silanes Feasible and Highly Efficient
Chemistry - A European Journal, Vol. 22, Núm. 12, pp. 4274-4284
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The Negishi Catalysis: Full Study of the Complications in the Transmetalation Step and Consequences for the Coupling Products
Organometallics, Vol. 35, Núm. 20, pp. 3604-3611
2015
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Organometallic Nucleophiles and Pd: What Makes ZnMe2 Different? Is Au Like Zn?
Organometallics, Vol. 34, Núm. 13, pp. 3120-3128
2014
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Cross alkyl-aryl versus homo aryl-aryl coupling in palladium-catalyzed coupling of alkyl-gold(I) and aryl-halide
Organometallics, Vol. 33, Núm. 13, pp. 3540-3545
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Diamine-catalyzed addition of ZnEt2to PhC(O)CF3: Two mechanisms and autocatalytic asymmetric enhancement
Chemistry - A European Journal, Vol. 20, Núm. 45, pp. 14800-14806
2013
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Stille coupling involving bulky groups feasible with gold cocatalyst
Angewandte Chemie - International Edition, Vol. 52, Núm. 8, pp. 2189-2193
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The decisive role of ligand metathesis in Au/Pd bimetallic catalysis
Chemical Communications, Vol. 49, Núm. 65, pp. 7246-7248
2012
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Bimetallic catalysis using transition and group 11 metals: An emerging tool for C-C coupling and other reactions
Chemistry - A European Journal, Vol. 18, Núm. 7, pp. 1864-1884
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ChemInform Abstract: Bimetallic Catalysis Using Transition and Group 11 Metals: An Emerging Tool for C-C Coupling and other Reactions
ChemInform, Vol. 43, Núm. 23, pp. no-no
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Strong metallophilic interactions in the palladium arylation by gold aryls
Angewandte Chemie - International Edition, Vol. 51, Núm. 20, pp. 4917-4920
2011
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Cationic intermediates in the Pd-catalyzed negishi coupling. Kinetic and density functional theory study of alternative transmetalation pathways in the Me-Me coupling of ZnMe2 and trans -[PdMeCl(PMePh2) 2]
Journal of the American Chemical Society, Vol. 133, Núm. 34, pp. 13519-13526
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Stille coupling of alkynyl stannane and aryl iodide, a many-pathways reaction: The importance of isomerization
Organometallics, Vol. 30, Núm. 3, pp. 611-617