Publicaciones (58) Publicaciones de JUAN ANGEL CASARES GONZALEZ

2022

  1. Copper(i) activation of C-X bonds: Bimolecular vs. unimolecular reaction mechanism

    Chemical Communications, Vol. 58, Núm. 16, pp. 2718-2721

  2. Pd/Cu bimetallic catalysis to access highly fluorinated biaryls from aryl halides and fluorinated arenes

    Chemical communications (Cambridge, England), Vol. 58, Núm. 19, pp. 3146-3149

2021

  1. Experimental study of the [ZnCl2(THF)2] catalyzed cis/trans-isomerization of [Pd(C6Cl2F3)Me(PPh3)2] and of the transmetalation of trans-[PdCl(C6Cl2F3)(PPh3)2] with [ZnMeCl(THF)2]

    Inorganica Chimica Acta, Vol. 517

  2. Transmetalation Reactions Triggered by Electron Transfer between Organocopper Complexes

    Inorganic Chemistry, Vol. 60, Núm. 15, pp. 11633-11639

2020

  1. Experimental and DFT Study of the [AuAr(AsPh3)]-Catalyzed cis/trans Isomerization of [PdAr2(AsPh3)2] (Ar = C6F5or C6Cl2F3): Alternative Mechanisms and Its Switch upon Pt for Pd Substitution

    Organometallics, Vol. 39, Núm. 12, pp. 2295-2303

  2. Kinetic study of the dynamic behavior of [M(C6F5)X(OpPyNPH3-N)] (M ) Pd, Pt; X ) C6F5, halide; n ) 1-3): Activation parameters for the restricted rotation about the m-aryl bond and for the py associative exchange

    Organometallics, Vol. 16, Núm. 4, pp. 770-779

2019

  1. 4 : An Extremely Efficient Catalyst for the Aryl Scrambling between Palladium Complexes

    Organometallics, Vol. 38, Núm. 4, pp. 739-742

  2. Intriguing Behavior of an Apparently Simple Coupling Promoter Ligand, PPh2(p-C6H4-C6F5), in Their Pd Complexes

    Organometallics, Vol. 38, Núm. 19, pp. 3688-3695

2018

  1. Comparing Protonolysis and Transmetalation Reactions: Microcalorimetric Studies of C-AuI Bonds in [AuRL] Complexes

    Inorganic Chemistry, Vol. 57, Núm. 17, pp. 11193-11200

2017

  1. Speciation of ZnMe2, ZnMeCl, and ZnCl2 in Tetrahydrofuran (THF), and Its Influence on Mechanism Calculations of Catalytic Processes

    ACS Catalysis, Vol. 7, Núm. 5, pp. 3575-3583

2016

  1. ChemInform Abstract: In situ Generation of ArCu from CuF<sub>2</sub>Makes Coupling of Bulky Aryl Silanes Feasible and Highly Efficient.

    ChemInform, Vol. 47, Núm. 31

  2. Dramatic mechanistic switch in Sn/AuI group exchanges: Transmetalation vs. oxidative addition

    Chemical Communications, Vol. 52, Núm. 23, pp. 4305-4308

  3. In Situ Generation of ArCu from CuF2 Makes Coupling of Bulky Aryl Silanes Feasible and Highly Efficient

    Chemistry - A European Journal, Vol. 22, Núm. 12, pp. 4274-4284

  4. The Negishi Catalysis: Full Study of the Complications in the Transmetalation Step and Consequences for the Coupling Products

    Organometallics, Vol. 35, Núm. 20, pp. 3604-3611

2015

  1. Organometallic Nucleophiles and Pd: What Makes ZnMe2 Different? Is Au Like Zn?

    Organometallics, Vol. 34, Núm. 13, pp. 3120-3128

2014

  1. Cross alkyl-aryl versus homo aryl-aryl coupling in palladium-catalyzed coupling of alkyl-gold(I) and aryl-halide

    Organometallics, Vol. 33, Núm. 13, pp. 3540-3545

  2. Diamine-catalyzed addition of ZnEt2to PhC(O)CF3: Two mechanisms and autocatalytic asymmetric enhancement

    Chemistry - A European Journal, Vol. 20, Núm. 45, pp. 14800-14806

  3. Palladium-mediated organofluorine chemistry

    Advances in Organometallic Chemistry (Academic Press Inc.), pp. 1-110

2013

  1. Stille coupling involving bulky groups feasible with gold cocatalyst

    Angewandte Chemie - International Edition, Vol. 52, Núm. 8, pp. 2189-2193

  2. The decisive role of ligand metathesis in Au/Pd bimetallic catalysis

    Chemical Communications, Vol. 49, Núm. 65, pp. 7246-7248