Química Física y Química Inorgánica
Fachbereich
PABLO
ESPINET RUBIO
Forscher in der Zeit 1986-2021
Publikationen, an denen er mitarbeitet PABLO ESPINET RUBIO (235)
2024
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Palladium (II) Precursors for Clean In Situ Formation of Ad Hoc Cross-Coupling Catalysts. Their Application in One-Pot/Two-Step Catalyses with 2-Biaryl-Dialkylphosphine Ligands
Advanced Synthesis and Catalysis, Vol. 366, Núm. 19, pp. 4145-4157
2023
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Intimate relationship between C-I reductive elimination, aryl scrambling and isomerization processes in Au(iii) complexes
Chemical Communications, Vol. 59, Núm. 14, pp. 1975-1978
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Problematic ArF-Alkynyl Coupling with Fluorinated Aryls. from Partial Success with Alkynyl Stannanes to Efficient Solutions via Mechanistic Understanding of the Hidden Complexity
Journal of the American Chemical Society, Vol. 145, Núm. 1, pp. 527-536
2022
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Access to luminescent mesophases of chiral gold(1>complexes by thermal or mechanic stimuli: the role of the tertiary carbon
Journal of Materials Chemistry C, Vol. 10, Núm. 3, pp. 941-946
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Pd/Cu bimetallic catalysis to access highly fluorinated biaryls from aryl halides and fluorinated arenes
Chemical communications (Cambridge, England), Vol. 58, Núm. 19, pp. 3146-3149
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Triphenylene-ethylammonium tetrachlorometallate salts: multicolumnar mesophases, thermochromism and Langmuir films
Journal of Materials Chemistry C, Vol. 10, Núm. 24, pp. 9222-9231
2021
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Expanding the Concepts Trans Influence and Back-Donation: Hybrid and Side Donations in [Cp*MIII(L)XY] (M = Rh, Ir) Complexes with CO, CN-, and CNR Ligands. A Window to Cis Influence
Inorganic Chemistry, Vol. 60, Núm. 18, pp. 14410-14417
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Striking ligand-disproportionative Cl/aryl scrambling in a simple Au(iii) system. Solvent role, driving forces and mechanisms
Chemical Communications, Vol. 57, Núm. 1, pp. 125-128
2020
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Experimental and DFT Study of the [AuAr(AsPh3)]-Catalyzed cis/trans Isomerization of [PdAr2(AsPh3)2] (Ar = C6F5or C6Cl2F3): Alternative Mechanisms and Its Switch upon Pt for Pd Substitution
Organometallics, Vol. 39, Núm. 12, pp. 2295-2303
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Experimental study of speciation and mechanistic implications when using chelating ligands in aryl-alkynyl Stille coupling
Dalton Transactions, Vol. 49, Núm. 32, pp. 11336-11345
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Fluorescent perylenylpyridine complexes: an experimental and theoretical study
Dalton Transactions, Vol. 49, Núm. 38, pp. 13326-13338
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Kinetic study of the dynamic behavior of [M(C6F5)X(OpPyNPH3-N)] (M ) Pd, Pt; X ) C6F5, halide; n ) 1-3): Activation parameters for the restricted rotation about the m-aryl bond and for the py associative exchange
Organometallics, Vol. 16, Núm. 4, pp. 770-779
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Ranking Ligands by Their Ability to Ease (C6F5)2NiIIL → Ni0L + (C6F5)2Coupling versus Hydrolysis: Outstanding Activity of PEWO Ligands
Inorganic Chemistry, Vol. 59, Núm. 24, pp. 18287-18294
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Striking Increase in Hole Mobility upon Metal Coordination to Triphenylene Schiff Base Semiconducting Multicolumnar Mesophases
Inorganic Chemistry, Vol. 59, Núm. 15, pp. 10482-10491
2019
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Li + and K + ionic conductivity in ionic nematic liquid crystals based on 18-diaza-crown ether substituted with six decylalkoxy-p-cyanobiphenyl chains
Journal of Materials Chemistry C, Vol. 7, Núm. 3, pp. 663-672
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Intriguing Behavior of an Apparently Simple Coupling Promoter Ligand, PPh2(p-C6H4-C6F5), in Their Pd Complexes
Organometallics, Vol. 38, Núm. 19, pp. 3688-3695
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New high-porosity polymer networks for advanced applications
Polímeros para el siglo XXI: X Congreso de Jóvenes Investigadores en Polímeros (JIP 2019). Universidad de Burgos, 20-23 mayo de 2019 (Burgos, España)
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Rh I Ar/Au I Ar′ Transmetalation: A Case of Group Exchange Pivoting on the Formation of M−M′ Bonds through Oxidative Insertion
Angewandte Chemie - International Edition, Vol. 58, Núm. 11, pp. 3501-3505
2018
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Comparing Protonolysis and Transmetalation Reactions: Microcalorimetric Studies of C-AuI Bonds in [AuRL] Complexes
Inorganic Chemistry, Vol. 57, Núm. 17, pp. 11193-11200
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Coordinatively Unsaturated [RhCp∗Rf2] (Cp∗ = C5Me5; Rf = C6F3Cl2-3,5), General Precursor to Cp∗-Diaryl and Cp∗-Halo-Aryl RhIII Complexes. Observing and Testing the Effect of Cp∗ as Electronic Buffer
Organometallics, Vol. 37, Núm. 20, pp. 3533-3542