Publications by the researcher in collaboration with PABLO ESPINET RUBIO (235)

2024

  1. Palladium (II) Precursors for Clean In Situ Formation of Ad Hoc Cross-Coupling Catalysts. Their Application in One-Pot/Two-Step Catalyses with 2-Biaryl-Dialkylphosphine Ligands

    Advanced Synthesis and Catalysis, Vol. 366, Núm. 19, pp. 4145-4157

2023

  1. Intimate relationship between C-I reductive elimination, aryl scrambling and isomerization processes in Au(iii) complexes

    Chemical Communications, Vol. 59, Núm. 14, pp. 1975-1978

  2. Problematic ArF-Alkynyl Coupling with Fluorinated Aryls. from Partial Success with Alkynyl Stannanes to Efficient Solutions via Mechanistic Understanding of the Hidden Complexity

    Journal of the American Chemical Society, Vol. 145, Núm. 1, pp. 527-536

2022

  1. Access to luminescent mesophases of chiral gold(1>complexes by thermal or mechanic stimuli: the role of the tertiary carbon

    Journal of Materials Chemistry C, Vol. 10, Núm. 3, pp. 941-946

  2. Pd/Cu bimetallic catalysis to access highly fluorinated biaryls from aryl halides and fluorinated arenes

    Chemical communications (Cambridge, England), Vol. 58, Núm. 19, pp. 3146-3149

  3. Triphenylene-ethylammonium tetrachlorometallate salts: multicolumnar mesophases, thermochromism and Langmuir films

    Journal of Materials Chemistry C, Vol. 10, Núm. 24, pp. 9222-9231

2021

  1. Expanding the Concepts Trans Influence and Back-Donation: Hybrid and Side Donations in [Cp*MIII(L)XY] (M = Rh, Ir) Complexes with CO, CN-, and CNR Ligands. A Window to Cis Influence

    Inorganic Chemistry, Vol. 60, Núm. 18, pp. 14410-14417

  2. Striking ligand-disproportionative Cl/aryl scrambling in a simple Au(iii) system. Solvent role, driving forces and mechanisms

    Chemical Communications, Vol. 57, Núm. 1, pp. 125-128

2020

  1. Experimental and DFT Study of the [AuAr(AsPh3)]-Catalyzed cis/trans Isomerization of [PdAr2(AsPh3)2] (Ar = C6F5or C6Cl2F3): Alternative Mechanisms and Its Switch upon Pt for Pd Substitution

    Organometallics, Vol. 39, Núm. 12, pp. 2295-2303

  2. Experimental study of speciation and mechanistic implications when using chelating ligands in aryl-alkynyl Stille coupling

    Dalton Transactions, Vol. 49, Núm. 32, pp. 11336-11345

  3. Fluorescent perylenylpyridine complexes: an experimental and theoretical study

    Dalton Transactions, Vol. 49, Núm. 38, pp. 13326-13338

  4. Kinetic study of the dynamic behavior of [M(C6F5)X(OpPyNPH3-N)] (M ) Pd, Pt; X ) C6F5, halide; n ) 1-3): Activation parameters for the restricted rotation about the m-aryl bond and for the py associative exchange

    Organometallics, Vol. 16, Núm. 4, pp. 770-779

  5. Ranking Ligands by Their Ability to Ease (C6F5)2NiIIL → Ni0L + (C6F5)2Coupling versus Hydrolysis: Outstanding Activity of PEWO Ligands

    Inorganic Chemistry, Vol. 59, Núm. 24, pp. 18287-18294

  6. Striking Increase in Hole Mobility upon Metal Coordination to Triphenylene Schiff Base Semiconducting Multicolumnar Mesophases

    Inorganic Chemistry, Vol. 59, Núm. 15, pp. 10482-10491

2019

  1. Li + and K + ionic conductivity in ionic nematic liquid crystals based on 18-diaza-crown ether substituted with six decylalkoxy-p-cyanobiphenyl chains

    Journal of Materials Chemistry C, Vol. 7, Núm. 3, pp. 663-672

  2. Intriguing Behavior of an Apparently Simple Coupling Promoter Ligand, PPh2(p-C6H4-C6F5), in Their Pd Complexes

    Organometallics, Vol. 38, Núm. 19, pp. 3688-3695

  3. New high-porosity polymer networks for advanced applications

    Polímeros para el siglo XXI: X Congreso de Jóvenes Investigadores en Polímeros (JIP 2019). Universidad de Burgos, 20-23 mayo de 2019 (Burgos, España)

  4. Rh I Ar/Au I Ar′ Transmetalation: A Case of Group Exchange Pivoting on the Formation of M−M′ Bonds through Oxidative Insertion

    Angewandte Chemie - International Edition, Vol. 58, Núm. 11, pp. 3501-3505

2018

  1. Comparing Protonolysis and Transmetalation Reactions: Microcalorimetric Studies of C-AuI Bonds in [AuRL] Complexes

    Inorganic Chemistry, Vol. 57, Núm. 17, pp. 11193-11200

  2. Coordinatively Unsaturated [RhCp∗Rf2] (Cp∗ = C5Me5; Rf = C6F3Cl2-3,5), General Precursor to Cp∗-Diaryl and Cp∗-Halo-Aryl RhIII Complexes. Observing and Testing the Effect of Cp∗ as Electronic Buffer

    Organometallics, Vol. 37, Núm. 20, pp. 3533-3542